Study on Medium Temperature Oxygen Pressure Leaching of Complex Sulfide Copper Nickel Slag and Synchronous Iron Precipitation
Received:June 30, 2024   Revised:July 24, 2024   Accepted:July 29, 2024      Published Online:September 11, 2024
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DOI:doi:10.3969/j.issn.1007-7545.2024.10.018
KeyWord:copper nickel sulfide slag; medium temperature oxygen pressure leaching; iron precipitation
                 
AuthorInstitution
QIN Shuchen 北京矿冶研究总院
ZHOU Qifan 矿冶科技集团有限公司
ZHENG Chaozhen 矿冶科技集团有限公司
SU Lifeng 矿冶科技集团有限公司
WANG Haibei 矿冶科技集团有限公司
LIU Sanping 矿冶科技集团有限公司
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Abstract:
      The experiments of medium temperature oxygen pressure leaching of Cu, Ni, Fe and S, and synchronous iron precipitation in complex sulfide copper nickel slag were carried out. The main elements in sulfide copper nickel slag were found out, and the effects of oxygen pressure leaching conditions on the leaching rate of Cu, Ni, Fe and S were investigated. The leaching rate of copper, nickel, iron and sulfur is 98.73%, 98.86%, 26.69%, 93.17%, respectively, the residual acid concentration in the leaching solution is 1.28 g/L, and the mass concentration of copper, nickel and iron in the leaching solution is 77.04, 18.80 and 0.67 g/L, respectively, under the optimum conditions including dosage of sulfuric acid (98%) of 20 g (i.e. 200 kg sulfuric acid per ton of copper-nickel slag), leaching temperature of 170 ℃, oxygen partial pressure of 0.4 MPa, liquid-solid ratio of 5 mL/g, and leaching time of 5 h.
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