Current Development Status of Clean Metallurgical Technologies for Antimony
Received:December 09, 2024   Revised:December 10, 2024   Accepted:December 11, 2024      Published Online:March 18, 2025
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DOI:doi:10.20237/j.issn.1007-7545.2025.04.004
KeyWord:antimony metallurgy; antimony sulfide concentrate; pyrometallurgical process; hydrometallurgical process; molten salt electrolysis
                    
AuthorInstitution
ZHU Qiang 中南大学
YANG Jianguang 中南大学
TANG Shiyang 中南大学
NAN Tianxiang 中南大学
LIU Jiang 中南大学
YE Wenlong 中南大学
TANG Chaobo 中南大学
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Abstract:
      Antimony is classified as a strategically advantageous metal in China, primarily sourced from the smelting and extraction of stibnite ore. Its compounds play an indispensable role in the production of flame retardants, alloy manufacturing, and photovoltaic glass. Currently, the predominant method for producing metallic antimony in China involves the "Blast furnace volatilization - Reverberatory furnace reduction" process. This process is characterized by a high coke rate and low oxygen concentration during smelting, resulting in the emission of large quantities of low-concentration SO?, thereby causing severe environmental pollution. In the context of China""s implementation of the "Dual carbon" strategic goals and comprehensive ecological environment management, achieving low-carbon and environmentally clean antimony smelting has become a critical issue for the sustainable development of the antimony smelting industry. The latest advancements in the development of green processes for antimony smelting were reviewed, the current technological status and research progress in stibnite ore smelting was comprehensively summarized, and the features of the new molten salt electrolysis technology for desulfurization and antimony production were highlighted. The aim is to provide recommendations and guidance for the green and sustainable development of the antimony smelting industry.
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